Hi Sandeep,
You have two options here :
1. You can view the PolicyStoreID using XPSConfig and copy it manually, it is just one ID.
For this, Open XPSConfig --> XPS --> Policy Store ID
2. Perform full policy store export (xpsexport c:\fullexport -xb -npass) and search for PolicyStoreID
<ConfigurationData>
<Vendor Name="CA">
<Product Name="XPS">
<ParameterName Name="PolicyStoreID">25ade49b-1cee-441e-bb48-d0f31188051b</ParameterName>
<ParameterName Name="SkipDictionaryCleanup"/>
<ParameterName Name="ExtractInputDir"/>
Hope this helps.
Regards,
Ujwol Shrestha
Ujwol's Single Sign-On Blog