We can implement this functionality using regular expressions in Compare Expressions assertions.
1 - Add Compare Expression assertion.
2 - Select 'Expression' and enter email parameter values ex: ${request.http.parameter.email}
3 - For Rules click 'Add' button.
4. - From Rule Selection pop-up select rule type 'Regular Expression' from the drop down options.
5 - Provide regular expression to validate the email format. For example:
[A-Z0-9._%+-]+@[A-Z0-9.-]+\.[A-Z]{2,}
For more information on regular expressions visit below URL:
Regular-Expressions.info - Regex Tutorial, Examples and Reference - Regexp Patterns
Regards
Kareem