By DevTest internal database, I assume you are referring to the Derby database that ships with the DevTest product. CA provides this instance of Derby to assist customers during the initial installation and usage of DevTest. This database is not designed nor recommended for long term usage.
CA advises customers to switch to a supported Enterprise DBMS package either during the installation procedure or as soon as possible after installation.
If your question refers to how to extend the databases maintained inside Derby, those actions are performed as they would be for any other DBMS. However, I would recommend against adding new tables or altering existing tables in the OOTB Derby databases as you could potentially break the product or create issues when migrating from one release to another.