We are attempting to monitor F5 VIPs and the Nodes behind the Virtual Listeners. Does CA UIM have this capability and if so is there documentation?
You need to use the snmpcollector for monitoring , there are a bunch of metrics snmpcollector can query from F5 Big IP. Take a look at the below link Supported Vendors --> F5 Networks
There are few metrics related to VIP (Virtual Server) available
UIM SNMP Device Support
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