The current GA releases of vmware probe do not support FIPS compliance. In order to get these probes to be FIPS compliant, they would have to be changed to add the FIPS Cryptography algorithm to the probes and then subject the probes to a full QA cycle to assure that the probes continue to work. FIPs support/compliance for the vmware probe or any other probe would be an enhancement request that can be submitted via the UIM User's forum, new ideas.
An alternate option is to disable FIPS but it seems that is not feasible.
https://support.microsoft.com/en-us/help/811833/system-cryptography-use-fips-compliant-algorithms-for-encryption-hashi
Security Settings > Local Policies > Security Options System cryptography: Set to Disabled.
You may need to set these registry settings to 0 per above MS Article.
HKLM\System\CurrentControlSet\Control\Lsa\FIPSAlgorithmPolicy\Enabled
HKLM\System\CurrentControlSet\Control\Lsa\ FIPSAlgorithmPolicy
Another customer found that downgrading the vmware probe from 6.x to a 4.x version to allow the probe to work under this scenario worked for them, but the feasibility of downgrading depends on what versions of vCenter you need to monitor.
Steve